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Metrohm 746 VA Trace Analyzer User Manual

Page 295

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5.6 Method Specifications

746 VA Trace Analyzer / 747 VA Stand

5-144

Parameter

Range; Default value / Meaning

Curve type

linear, nonlin; linear

Curve type for standard addition

The measured values obtained in the standard addition can be
evaluated with a linear or a non-linear function (see also section

6.9.4):

linear

Straight line of type y = bx
Calculation by weighted linear regression

y:

EV

Evaluation value (A, W or s)

x:

ρ

eff

Effective mass concentration in the
analysis solution

b:

Slope

Slope of the line

Y.reg

Estimated

EV

value for sample con-

centration

ρ

eff,s

Y.reg

Slope

0

0

EV

ρρ

eff

eff

std.add., linear

nonlin

Curve of type y = bx + cx

4

Calculation by weighted curve matching

y:

EV

Evaluation value (A, W or s)

x:

ρ

eff

Effective mass concentration in the
analysis solution

b:

Slope

Slope of the line in the linear region

c:

Nonlin.

Non-linearity factor

Y.reg

Estimated

EV

value for sample con-

centration

ρ

eff,s

Slope

Y.reg

0

0

EV

ρρ

eff

eff

std.add., nonlin

1

st

standard addition

2

nd

standard addition

3

rd

standard addition

Sample

3

rd

standard addition

2

nd

standard addition

1

st

standard addition

Sample