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Metrohm viva 1.0 (process analysis) User Manual

Page 628

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5.6 Evaluation subwindow

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viva 1.0 (for Process analysis)

Units for results

Name

Symbol

Unit

Mass

m

g

Volume

V

L

Mass concentration

c

g/L

Volume concentra-
tion

c

L/L

Substance concentra-
tion

c

mol/L

Time

t

s

Current

I

A

Amount of substance

n

mol

Electrical charge

Q

C = As

Electrical potential

U

V = WA

-1

5.6.7.2

Result calculation from calibration curves and error calculation

For all three possible calibration methods, the concentration (e.g. a mass
concentration, a volume concentration or a molar concentration) must be
determined in the measuring vessel with the help of a calibration curve.
This calibration curve itself must be determined by the measurement of
solutions for which the concentrations are known. The parameters for a
specified linear or non-linear curve function are then calculated from the
value pairs Evaluation quantity / concentration. Because of the fact
that, as a general principle, the calculations of the calibration curves and
of the results based upon them, in addition to the associated error calcula-
tion, remain the same for all calibration methods, the calculation proce-
dure that is applied shall be described in general terms in the following.

The connection between the variables x and y are sought on the basis of
the measured values x

i

, y

i

, for which it is assumed that the following pre-

requisites apply: