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Standard addition curves are not reproducible, 10 na, 1 μa – Metrohm 797 VA Computrace User Manual

Page 276: 10 μa, 9 troubleshooting, Highest current range, Lowest current range, 797 va computrace – software

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9 Troubleshooting

797 VA Computrace – Software

264

Example:
(For all measurements: Amplitude: 0.02 V , Frequency: 50 Hz)

Highest current range

: 10

nA

Lowest current range

: 10 nA

Zn/Cd/Pb/Cu-Determination/DIN-Puffer/SqW

Test Si_kap_nullserie

-1.00

-0.80

-0.60

-0.40

-0.20

0.00

U (V)

120n

140n

160n

180n

I (

A

)

Cd

Cu

Pb

Zn

Highest current range

: 1

μA

Lowest current range

: 1 μA

Zn/Cd/Pb/Cu-Determination/DIN-Puffer/SqW

Test Si_kap_nullserie

-1.00

-0.80

-0.60

-0.40

-0.20

0.00

U (V)

0

20.0n

40.0n

60.0n

80.0n

100n

120n

I (

A

)

Cd

Zn

Cu

Pb

Highest current range

: 10

μA

Lowest current range

: 10 μA

Zn/Cd/Pb/Cu-Determination/DIN-Puffer/SqW

Test Si_kap_nullserie

-1.00

-0.80

-0.60

-0.40

-0.20

0.00

U (V)

0

20.0n

40.0n

60.0n

80.0n

100n

120n

I (

A

)

Zn

Cu

Pb

Cd

Standard addition curves are not reproducible

With all types of electrodes:
1. Check method parameters (stirring time, etc.).