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Contamination potential, Chloride potential, Calibration factor z – Metrohm 797 VA Computrace User Manual

Page 207: Suppressor, Brightener

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6.4 Some Definitions used with CVS and CPVS

797 VA Computrace – Software

195

Contamination potential

The Contamination potential correlates with the concentration of
organic degradation products in the electroplating bath. It is used
with the Calibration techniques LAT Standard addition for bright-
eners and MLAT Standard addition for brighteners (with the modi
CVS and CPVS).

Chloride potential

The Chloride potential correlates with the concentration of chloride
in the electroplating bath. It is used with the Calibration techniques
LAT Standard addition for brighteners and MLAT Standard addition
for brighteners (with the modi CVS and CPVS).

Calibration factor Z

The “Calibration factor” Z is determined with the

Calibration

tech-

nique “DT Record calibration curve”.
It is used for the Suppressor determination with the

Calibration

technique “DT Suppressors with calibration curve”.

It is calculated from the following equation:

Std

VMS

Std

Std

V

V

c

V

Z

+

=

Std

V

Is the volume of Suppressor standard solution at the
“Evaluation ratio”.

Std

c

Is the concentration of Suppressor standard solution.

VMS

V

Is the volume of VMS (Virgin Make-up Solution).

Z is equal to the Suppressor concentration in the measurement cell
at the “Evaluation ratio”.

Suppressor

Any of various components of electroplating bath solutions that
suppresses plating.

Brightener

Any of various components of electroplating bath solutions that in-
creases the deposition during plating.