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Rc record response curve – Metrohm 797 VA Computrace User Manual

Page 195

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6.2 Calibration techniques with CVS and CPVS

797 VA Computrace – Software

183

Regression technique [ read only ]

The regression technique is displayed.

Peak evaluation [ Coulometric ] [ read only ]

Selection of peak evaluation quantity:

Coulometric

Charge transmitted during the peak.

Smooth factor [ 1...6 ; 4 ]

Smoothing power of the Savitzky/Golay smooth-
ing of the baseline (1 = minimum smoothing, 6 =
maximum smoothing) (s

ee

Smoothing and differ-

entiation

, section 5.8

).

Eliminate spikes

Eliminates spikes to smooth the signal.

Reverse sweep [ on, off ; off ]

Enable peak evaluation of the reverse sweep of
cyclic sweeps (not available with CPVS).

Endpoint and evaluation criteria

Begin of evaluation Q/Q(0) [ read only ]

Only the measuring points between the „Begin of
evaluation“ and the „Evaluation ratio“ are used for
the calculation of the regression (linear, nonlinear
and quadratic).

RC Record response curve

"RC Sample with response curve" is a "Response Curve Technique"
which can be used with the CVS and CPVS mode). The Response
Curve is a normalized calibration curve for electroplating bath addi-
tives with suppressing impact. The "Response Curve Technique" is
used for the determination of Suppressor in electroplating baths if
the "Dilution Titration Technique" can't be applied.
The response curves recorded with this

Calibration

technique are

used together with

Calibration

technique "RC Sample with respon-

se curve" to determine Suppressor concentrations.

Note:

A determined response curve file can only be adopted auto-

matically if the checkbox

Save calibration curves additionally with-

out date and time

on the

General

tab of the

GENERAL SETTINGS

window is checked.

Determination tab with Calibration technique “RC Record
response curve”

The

Determination

tab of the

EDIT WORKING METHOD PARAME-

TERS

window contains general specifications for performing the

determination. The parameters displayed depend on the selected

Calibration

technique and measurement

Technique

. With “RC Re-

cord response curve” following parameters have to be

defined: