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Metrohm 794 Basic Titrino User Manual

Page 159

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5.2 Connection of electrodes, preparing titration vessel

794 Basic Titrino

155

5.2 Connection of electrodes, preparing titration ves-

sel

Ref

Connection for separate reference electrode.

Input is free when a combined electrode is used.

Pol

Connection of polarized electrodes.

If measured quantities Ipol or Upol are selected, this

measuring input is automatically active.

Ind I
Ind II

Connection of pH, redox, ISE electrodes.

Combined or separate electrodes. Select measuring input

1 or 2 in the Titrino.

Important:

The measuring inputs 1 and 2 have a common reference.

They may therefore be used as a differential measuring

input see below. However, only one reference electrode

can be used in the same vessel!

Pt100/

1000

Connection of a temperature sensor Pt100 or Pt1000..

Differential potentiometry

In potentiometric measurements in media of low conductivity, e.g. in

organic solvents, high-impedance electrode assemblies such as pH

electrodes record noise voltages which arise from stray electrostatic

and electromagnetic fields. Particularly high field strengths occur

through friction at insulators such as plastic floors, synthetic clothing,

etc.; conditions which can appear in every normal laboratory envi-

ronment.

Problems of this type can be solved by measurement using a differ-

ential amplifier. Here, the indicator and reference electrode are each

connected to a high-impedance measuring input. It is important to

ensure that both electrodes have identical shielding and are thus

symmetrical with regard to the recording of noise signals. An auxil-

iary electrode provides the electrical connection between the refer-

ence point of the amplifier circuit and the measurement solution.

Recommended electrodes:

Meas.input Manual determinations

Sample Changers

Ind I

6.0133.100 pH Glass electrode

6.0130.100 pH Glass electrode

Ind II

6.0729.100 double-shielded

Ag/AgCl reference electrode

6.0729.110 double-shielded

Ag/AgCl reference electrode

Ref

6.0301.100 auxiliary electrode

6.0302.110 auxiliary electrode

Ref

Pol

Ind I

Ind II

Rear panel:

Pt 100/1000