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Chapter 9 measurement and theory, 1 speed of sound and gas composition, Chapter 9 – INFICON Composer Elite Gas Concentration Monitor User Manual

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Composer Elite Operating Manual

Chapter 9

Measurement and Theory

9.1 Speed of Sound and Gas Composition

The speed of sound,

C

, in an ideal gas is equal to:

[1]

where:

= 1.4 for Air

[2]

T

= Kelvin temperature

R

= Universal Gas Constant = 8.3143 x 10

7

erg/(Mole K)

M

= Molecular Weight (AMU)

Equation [1] may be expanded for binary mixtures by modifying the Specific Heat
Ratio and molecular weight to account for the Mole Fraction of component two,

x

,

as follows.

[3]

[4]

So the speed of sound of the mixtures,

CM

, is:

[5]

which holds for any ideal mixture; that is, a mixture that is formed without change
in volume.

C

RT

M

----------

=

C

p

C

v

------

Heat Capacity at Constant Pressure

Heat Capacity at Constant Volume

---------------------------------------------------------------------------------------

=

=

1

x

1

1

--------------

1 x

2

1

--------------

+

1

+

=

M

xM

1

1 x

M

2

+

=

C

M

RT

M

----------

=