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Methods – Hanna Instruments HI 901 User Manual

Page 78

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METHODS

This calculation formula is used as an approximation of the sample concentration (sample

max conc.). This formula can be used when we have an expected sample concentration (eg.

we know that the sample concentration must be around 1 M (mol/L)).

If we don’t have an expected sample concentration, then from the View/Modify Method screen:

• highlight the Titrant 1 Entry option, by pressing

.

• highlight Fixed By User option and press

, you will be prompted to type the

volume of titrant 1 to be dispensed in the first stage of the back titration.

With this approximation, the titrator will calculate the volume of titrant 1 needed to consume

the sample and multiply it by an excess factor in order to raise or to lower the amount of

titrant 1 dispensed.
When the parameters from the formula are set, press

to proceed to the next formula

used in the back titration algorithm.

This formula is used to calculate the remaining volume of titrant 1 after the reaction with the

sample.

In order to calculate this volume, the remaining volume of titrant 1 is titrated (pH/mV

equivalence point titration) with the titrant 2.

After the excess (remaining) volume of titrant 1 is calculated, the following formula is used

to calculate the exact volume of titrant 1 that was consumed by the sample:

V1 = V1tot – V1excess

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