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Waters Oligonucleotide Separation Technology ACQUITY UPLC C18 Column User Manual

Method guidelines, Acquit y uplc, Ost c

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[ method guidelines ]

ACQUITY UPLC

®

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columns are based on Waters second gen-

eration of hybrid-silica BEH Technology™ particles and can be effec-
tively used for the high resolution analyses of detritylated synthetic
oligonucleotides using ion-pair, reversed-phase chromatography. This
document provides useful method guidelines for the effective use of
this column chemistry for this group of compounds.

Contents

I.

PRINCIPLES OF OLIGONUCLEOTIDE SEPARATIONS

II. SAMPLE PREPARATION

III. RECOMMENDED MOBILE PHASES

IV. RECOMMENDED INJECTOR WASH SOLVENTS

V. SOLVENT MIXING OPTIONS

VI. DEVELOPING SEPARATIONS

VII. ANALYSIS OF MODIFIED OLIGONUCLEOTIDES

ACQUIt Y UPLC

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*ost: oLIgonUCLeotIde sePArAtIon teChnoLogY