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Waters GlycoWorks High-throughput Sample Preparation Kit User Manual

Care and use manual, Glycoworks high-throughput sample preparation kit

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GlycoWorks High-throughput Sample Preparation Kit

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[ CARE AND USE MANUAL ]

LC-FLR

LC-FLR-MS

I. INTRODUCTION

This document provides information regarding the general care and
use of the Waters GlycoWorks™ High-throughput Sample Preparation
Kit for release of N-glycans. This protocol can be used as a guideline
and is validated using IgG but can also be used and optimized for
other N-linked glycoproteins. This sample preparation offers an
inclusive protocol that allows the user to source many of the critical
components needed to perform the preparation from one vendor.

The 96-well plate is good for 48 analyses.

For expected results using the protocol with the control standard,
please see Reference 1.

The guide provides the following:

An instruction template for new users that highlights the use of a

control standard (included in the kit) for first time validation as
well as subsequent troubleshooting

Protocol for LC/FLR and LC/FLR/MS

Tips and tricks throughout each section to help aid in the success

An online training video is also available (see Reference 3)

GlycoWorks High-throughput Sample Preparation Kit

CONTENTS

I. INTRODUCTION

II. STORAGE AND DISPOSAL OF PLATES

III. ABBREVIATIONS

IV. USING THE GLYCOWORKS HIGH-THROUGHPUT KIT

V. PREPARING LABELED GLYCANS FOR HILIC-FLR WITH

AN ACQUITY UPLC BEH GLYCAN COLUMN

VI. REFERENCES

VII. ORDERING INFORMATION

Figure 1: Sample Preparation from Glycoprotein to Labeled Glycans

Glycoproteins

FLR Labeling Reaction of Glycans

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FLR Labeled Glycans

MALDI MS

Denaturation and Deglycosylation

RapiGest™ (if necessary)

DTT Reduction (if necessary),
IAM Alkylation (if necessary)
Deglycosylation by PNGase F

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Extraction of Released Glycans

GlycoWorks HILIC µElution Plate

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Excess Labeling Reagent Removal

GlycoWorks HILIC µElution Plate

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General Guideline of Sample Preparation from Glycoprotein to
enrich FLR Labeled Glycans Using Reductive Amination Reaction.

If using MALDI please refer to Product Solution, Literature Code 720004660EN