Canon PIXMA MP250 - Manual (Page 255)

5. Select the paper size
Select Youkei 4, Youkei 6, Comm.Env. #10, or DL Env. in the Envelope Size Setting dialog box, and
then click OK.
6. Set the orientation
To print the addressee horizontally, select Landscape for Orientation.
7. Select the print quality
Select High or Standard that matches your purpose for Print Quality.
8. Complete the setup
Click OK.
When you execute print, the information is printed on the envelope.
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Page 255 of 678 pages Printing an Envelope