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LaMotte SMART3 Colorimeter User Manual

Page 245

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pH

COLORIMETRIC METHOD • CODE 3700-01-SC

QUANTITY

CONTENTS

CODE

60 mL

Chlorphenol Red Indicator

V-2209-H

60 mL

Phenol Red Indicator

V-2304-H

60 mL

Thymol Blue Indicator

V-2213-H

3

Pipets, 0.5 mL, plastic w/caps

0369

The term pH (always written with a lower case p and an upper case H) is correctly

defi ned as the negative logarithm of the hydrogen ion concentration. More simply,

the term pH can be considered to be an index of the amount of hydrogen ion

present in a substance, or is a measure of the acidity of the substance. This index

is important as it can be used to quickly identify the acid, neutral or alkaline (basic)

nature of materials. Acidic substances have a pH less than 7.0, neutral substances

have a pH equal to 7.0 and alkaline substances have a pH greater than 7.0.

Most natural waters have pH values from pH 5.0 to pH 8.5. Acidic, freshly fallen

rain water may have a pH value of pH 5.5 to pH 6.0. When it reacts with soils and

minerals containing weakly alkaline materials, the hydroxyl ion concentration will

increase and the hydrogen ion concentration will decrease. Then the water may

become slightly alkaline with a pH of 8.0 to 8.5. Natural sea water has a pH value

of 8.1, and changes from this value indicate that water from an inland source is

entering the body of sea water.

Waters more acidic than pH 5.0 and more alkaline than pH 8.5 to 9.0 should be

viewed with suspicion. Mine drainage and acidic industrial wastes are the principal

factors in increasing the acidity of water, and alkaline industrial wastes are the

cause of high pH values.

Because pH measurements can be made so simply, and because they can tell so

much about the past and future reactions of water, they are routinely made in water

quality studies. Sudden changes in pH values serve as warning signals that water

quality may be adversely affected through the introduction of contaminants.

SMART3 Test Procedures 11.10

pH

Test P

rocedures