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Titration theory – Hanna Instruments HI 903 User Manual

Page 217

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TITRATION THEORY

C sample1

Sample 1 Concentration (g/100g)

C sample2

Sample 2 Concentration (g/100g)

C sample3

Sample 3 Concentration (g/100g)

V titrant 1

Volume of titrant required to reach the first end point (L)

V titrant 2

Volume of titrant required to reach the second end point (L)

V titrant 3

Volume of titrant required to reach the third end point (L)

C titrant

Concentration of titrant (N)

Ratio

Equivalence ratio of analyte/ titrant (mol analyte/ eq titrant)

FW analyte 1

Formula Weight of the Analyte 1 (g/mol)

FW analyte 2

Formula Weight of the Analyte 2 (g/mol)

FW analyte 3

Formula Weight of the Analyte 3 (g/mol)

m sample

Weight of Sample (mL)

5.2.5 Back Titration

The equation used in back titration calculations is also similar to the equation for a blank
titration. Instead of subtracting the initial amount of titrant needed to react with the blank,
the amount of second titrant needed to react with the excess titrant added in the first titration
is subtracted from the amount of the first titrant added. The difference between the two
amounts is the amount of titrant necessary to reach the first equivalence point.

C sample

Sample Concentration (g/100mL)

C titrant 1

Concentration of titrant 1 (N)

V titrant 1

Volume of titrant 1 (L)

C titrant 2

Concentration of titrant 2 (N)

V titrant 2

Volume of titrant 2 (L)

Ratio

Equivalence ratio of analyte/ titrant (mol analyte/ eq titrant)

FW analyte

Formula Weight of the analyte (g/mol)

V sample

Volume of sample (mL)