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Fluoride – LaMotte SMART Spectro Spectrophotometer User Manual

Page 140

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FLUORIDE

SPADNS METHOD • CODE 3647-01-SC

QUANTITY

CONTENTS

CODE

4 x 30 mL

* Acid-Zirconyl-SPADNS Reagent

*3875-G

60 mL

* Sodium Arsenite Solution

*4128-H

1

Pipet, 0.5 mL, plastic

0353

1

Pipet, 1.0 mL, plastic

0354

*WARNING: Reagents marked with a * are considered to be potential health hazards. To view
or print a Material Safety Data Sheet (MSDS) for these reagents see MSDS CD or
www.lamotte.com. To obtain a printed copy, contact LaMotte by e-mail, phone or fax.

Fluoride may occur naturally in some ground waters or it may be added to
public drinking water supplies to maintain a 1.0 mg/L concentration to prevent
dental cavities. At higher concentrations, fluoride may produce an
objectionable discoloration of tooth enamel called fluorosis, though levels up
to 8 mg/L have not been found to be physiologically harmful.
þNOTE: This procedure uses the EPA approved Reagent System for fluoride

found in method 4500-F-D, 18th Edition of Standard Methods, page 1-27.

APPLICATION

Drinking and surface waters; domestic and industrial waters.

RANGE:

0.00–2.00 ppm Fluoride

METHOD:

Colorimetric test based upon the reaction between fluoride
and zirconium dye lake. The fluoride reacts with the dye
lake, dissociating a portion of it into a colorless complex ion
and dye. As the fluoride concentration increases, the color
produced becomes progressively lighter.

SAMPLE
HANDLING &
PRESERVATION:

Samples may be stored and refrigerated in plastic containers.

SMART SPECTRO TEST PROCEDURES 05.04

Fluoride 1/3