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Specifications, Measurement specifications, Specifications 21 – Campbell Scientific TGA100 Trace Gas Analyzer Manual User Manual

Page 21: Table 1. typical concentration measurement noise

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1.7 Specifications

1.7.1

Measurement Specifications

Sample Rate: 10 Hz

Averaging Period: 0.1 sec

Sample cell volume: 480 ml

Frequency Response (@ 4.8 liter/sec actual flow rate): 3 Hz

The TGA100 frequency response is determined by the averaging time (0.1 s) and the time for a new sample to fill the
sample cell. The frequency response was measured at 14.4 slpm flow rate and 50 mbar sample pressure (4.8 actual l/s)
by injecting 1 µl of N

2

O into the sample stream. The resulting time series and frequency response graphs are shown in

.

Figure 1-9

Figure 1-9. TGA100 Impulse Response (left) and Frequency Response (right)

0.0

0.5

1.0

1.5

2.0

0

1

2

3

4

Concentration (ppmv)

Time (sec)

0.1

1

5

0.01

0.1

1

Frequency Response

Frequency (Hz)

The typical 10 Hz concentration measurement noise, given in

, is calculated as the square root of the Allan

variance with no averaging (i.e. the two-sample standard deviation. This is comparable to the standard deviation of the
10 Hz samples calculated over a relatively short time (10 s). The typical 30-minute average gradient resolution is given
as the standard deviation of the difference between two intakes, averaged over 30 minutes, assuming typical valve
switching parameters.

Table 1

Table 1. Typical Concentration Measurement Noise

Gas Wave

number

(cm

-1

)

10 Hz Noise

(ppbv)

30-min Gradient

Resolution (pptv)

Nitrous Oxide

N

2

O 2208.575

1.5

30

Methane CH

4

3017.711

7

140

Ammonia NH

3

1065.56

6

200

Carbon Monoxide

CO

2176.284

3

60

Nitric Oxide

NO

1900.08

13

260

Nitrogen Dioxide

NO

2

1630.33

3

60

Sulfur Dioxide

SO

2

1366.60

25

500

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