Metrohm NIRS XDS MasterLab Analyzer - Manual (Page 65)

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below, this is automatic.
At the bottom of the Vial Dialog screen is a
checkbox marked “Use Order”.
If this box is checked, the MasterLab Analyzer
will start with the sample marked “1” in the
“Order” column, and proceed numerically
upward through the order designated in the
“Order” column.
If this box is left unchecked, the MasterLab
Analyzer will proceed from vial position 1, to 2,
to 3, in numerical order of the physical vial
position in the tray. Vision will ignore the
“Order” column.
If the user plans to enable “Use Order” it is
important to set the order correctly.
Fortunately there is a method to set order easily, without losing Sample ID information.