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Appendix, Appendix 8.1 ph as a function of mv – KROHNE OPTISENS PAS 2000 EN User Manual

Page 38

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8

APPENDIX

38

OPTISENS PAS 2000

www.krohne.com

11/2008 • MA PAS 2000 R04 en

Appendix

8.1 pH as a function of mV

The pH-value is the negative logarithm of the hydrogen ion concentration, and it is directly
related to the proportion of hydrogen ions H

+

to hydroxide ions OH

-

in the media. The pH-

electrode measures excess or deficit of the hydrogen ions and gives a proportional millivolt
signal as output. The signal is 59.16 mV per 1 pH at 77°F. In clean water there is a total balance
between hydrogen ions and hydroxide ions, the output from the electrode is 0.0 mV and pH is 7.
The millivolt signal is measured by PAS 2000 pH and the corresponding pH is calculated in
MAC 080.

mV

pH

H

+

ions, mol/l

OH

-

ions, mol/l

Example

414

0

1

0.00000000000001

355

1

0.1

0.0000000000001

296

2

0.01

0.000000000001

Coca Cola

237

3

0.001

0.00000000001

177

4

0.0001

0.0000000001

Orange juice

118

5

0.00001

0.000000001

59

6

0.000001

0.00000001

Milk

0

7

0.0000001

0.0000001

Clean water

-59

8

0.00000001

0.000001

Blood

-118

9

0.000000001

0.00001

-177

10

0.0000000001

0.0001

-237

11

0.00000000001

0.001

-296

12

0.000000000001

0.01

-355

13

0.0000000000001

0.1

-414

14

0.00000000000001

1

Sulfa

.book Page 38 Friday, November 28, 2008 2:32 PM