beautypg.com

Experiment 2: isothermal processes, Experiment 2a: boyle’s law – PASCO TD-8565 Adiabatic Gas Law Apparatus User Manual

Page 7

background image

© 2009 Physics Enterprises

7

Target Students

High school and introductory college physics and chemistry.

Objectives

To observe that PV = const for constant temperature.

Physical Principles

When a process occurs with the system in contact with a heat reservoir to keep the
temperature fixed the process is considered “isothermal.” For such a process, the pressure is
inversely related to the volume, i.e.,

(2.1a)

Since Eq. (2.1a), Boyle’s Law, can be rewritten as

(2.2a)

one sees that a plot of ln(P) vs. ln(V) should be a straight line with a slope of –1.

const

PV

=

( )

( ) (

)

const

V

P

ln

ln

ln

+

=

Procedure

Convert voltages to Pressure and Volume as in Experiment I using the Calculator in Data
Studio
. Set up a graph of P vs. V.

Follow the procedure for the ideal gas law measurements (Experiment I) but slow the

Sample rate to one second and perform the compression slowly and steadily (quasi-
statically) over the course of a minute-or-so. This allows the temperature of the gas to always
remain at room temperature (isothermal). McNairy [1] recommends suspending a bucket
from the end of the handle and easing weights into the bucket. As you collect data, you can
watch the Pressure adjust to the slow change in Volume.

Experiment 2: Isothermal Processes

Experiment 2A: Boyle’s Law