3 photoacoustic detection – Quantum Instruments Cascade Laser Starter Kit User Manual
Page 55

Starter Kit Instruction Manual
Maintenance
54
9.1.3
Photoacoustic detection
In the photoacoustic detection, the optical beam is
periodically modulated in amplitude before illumi-
nating the cell containing the absorbing chemical.
The expansion generated by the periodic heating
of the chemical creates an acoustic wave which is
detected by a microphone.
The two very important advantages of photoa-
coustic detection are:
• a signal is detected only in the presence of
absorption from the molecule;
• no mid-IR detectors are needed.
For these reasons, photoacoustic detection has
the potential of being cheap and very sensitive. How-
ever, ultimate sensitivity is usually limited by the
optical power of the source.
QC Laser
Chemical Cell
Microphone
w
Detection of the
acoustic wave at
w
a.c. modulation of
the laser amplitude
Fig.53: Photoacoustic technique