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Calibration standards, Nbs ph buffers – Ionode IJ pH V5.1 User Manual

Page 22

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Ionode IJ Instruction Manual

22

4.5. Calibration Standards

4.5.1. NBS pH Buffers

pH 4.01: 0.05M Potassium Hydrogen Phthalate
Dissolve

10.12g

of

potassium

hydrogen

phthalate in distilled water and make up to 1L.

pH 6.87: 0.025M Potassium Dihydrogen
Phosphate / 0.025M Disodium Hydrogen
Phosphate
Dry each salt at 120

o

C for 2 hours and then

cool in a desiccator. Dissolve 3.533g disodium
hydrogen phosphate and 3.388g potassium
dihydrogen phosphate in distilled water and
make up to 1L.

pH 7.413: 0.008695M Potassium Dihydrogen
Phosphate / 0.03043M Disodium Hydrogen
Phosphate
Prepare salts as above and dissolve 1.179g
potassium dihydrogen phosphate and 4.302g
disodium hydrogen phosphate in distilled water
and make up to 1L.

pH

9.18:

0.01M

Sodium

Tetraborate

Decahydrate
Dissolve

3.80g

of

sodium

tetraborate

decahydrate (borax) in distilled water and make
up to 1L. This solution is susceptible to pH
change from carbon dioxide and should be
prepared fresh regularly.

pH 10.01: 0.025M Sodium Bicarbonate /
0.025M Sodium Carbonate
Use anhydrous reagent grade salts to prepare
this

buffer.

Dissolve

2.092g

of

sodium

bicarbonate and 2.640g of sodium carbonate in
distilled water and make up to 1L.