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Appendix: catalytic combustor, Encore woodburning stove – Vermont Casting 2550 User Manual

Page 33

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Encore Woodburning Stove

2000956

Appendix: Catalytic Combustor

In any chemical reaction, including the combustion

process, there are certain conditions which must be

met before the reaction can take place. For example, a

reaction may require a certain temperature, or a certain

concentration of the reactants (the combustion gases

and oxygen), or a certain amount of time. Catalysts,

though not changed themselves during the reaction,

have the ability to act at a molecular level to change

these requirements. In the Encoreʼs secondary com-

bustion chamber the catalyst reduces the temperature

at which secondary combustion can start from the 1000

- 1200°F (540 - 650°C) range to the 500 - 600°F (260

- 315°C) range, increasing efficiency, and reducing

creosote and emissions.
The catalytic reaction does have some limitations of its

own. Primary among these is that the reactants (the

gases) come into close physical contact with the cata-

lyst itself.
To ensure the necessary contact, the catalytic element

in your Encore is composed of a ceramic base in the

shape of a honeycomb. Each of the honeycombʼs many

surfaces carries a coating of the catalyst (usually a

noble metal such as platinum or palladium). The large

surface area exposed in this form ensures that the com-

bustion gases have the greatest opportunity to come in

contact with the catalyst.
Loss of catalytic activity will be apparent in several

ways. First you may notice an increase in fuel con-

sumption. Second, there will be a visible increase in the

rate at which creosote builds up in your chimney con-

nector system. You may also notice a heavy discharge

of smoke from the chimney. There are a number of
catalytic problems which can cause loss of activity:

Blockage

While the honeycomb pattern ensures good contact, it

also increases the resistance to flow of the combustion

gases, and, because of the many surfaces, provides

more places for creosote and fly ash to deposit. It is

important to follow the operating instructions in order

to minimize these deposits, and to periodically inspect

your catalyst for signs of blockage.

Masking and Poisoning

While the catalyst itself does not enter into the combus-

tion process, certain elements, such as lead and sulfur,

can attach to the active sites on the surface of the hon-

eycomb. Though the catalyst is still there, it is covered,

or masked, by the contaminant, and cannot function. To

avoid this situation, it is important not to burn anything

in your Encore that is a source of these contaminants.

Particularly avoid painted or treated wood, coal, house-

hold trash, colored papers, metal foils, or plastics.

Chemical chimney cleaners may also contain harmful

elements. The safest approach is to burn only untreat-

ed, natural wood.

Flame Impingement

The catalytic element is not designed for exposure to

direct flame. If you continually overfire your Encore, the

chemistry of the catalyst coating may be altered, inhibit-

ing the combustion process.
Thermal degradation of the ceramic base may also oc-

cur, causing the element to disintegrate. Stay within the
recommended guidelines of the Operation section.

Mechanical Damage

If the element is mishandled, damage may occur.

Always treat the element carefully. Remember the cata-

lyst is made of a ceramic material; treat it as you would

fine china. Hairline cracks will not affect the perfor-

mance of the catalyst, as long as the steel sleeve holds

the element in the proper position.

Peeling

The surface coat may peel if the catalytic element is

frequently subjected to excessive temperatures. Follow

the operating instructions carefully to avoid this type of

damage.

General

Every Vermont Castingsʼ Encore is equipped with either

a Corning “Long-Life”

®

or a Technical Glass Products

“Honeycomb”

®

combustor. The products are equivalent.

If you must ship your catalytic element for any reason,

remember its fragile nature. Place the element in a

plastic bag, and package it with a generous amount of

shock absorbing material.