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Principle of operation, Specifications, Precision and accuracy – Hanna Instruments HI 96725 User Manual

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PRINCIPLE OF OPERATION

Absorption of Light is a typical phenomenon of interaction between electromagnetic radiation and
matter. When a light beam crosses a substance, some of the radiation may be absorbed by
atoms, molecules or crystal lattices.
If pure absorption occurs, the fraction of light absorbed depends both on the optical path length
through the matter and on the

physical

-chemical characteristics of the substance according to the

Lambert-Beer Law:

-log

I

/

I

o

=

ε

λ

c d

or

A

=

ε

λ

c d

Where:

-log

I

/

I

o

=

Absorbance (A)

I

o

=

intensity of incident light beam

I

=

intensity of light beam after absorption

ε

λ

=

molar extinction coefficient at wavelength

λ

c

=

molar concentration of the substance

d

=

optical path through the substance

SPECIFICATIONS

Range

Free Cl

2

0.00 to 5.00 mg/L

Total Cl

2

0.00 to 5.00 mg/L

Cyanuric Acid

0 to 80 mg/L

pH

6.5 to 8.5

Resolution

0.01 mg/L from 0.00 to 3.50 mg/L Cl

2

0.10 mg/L above 3.50 mg/L Cl

2

1 mg/L Cyanuric Acid
0.1 pH

Accuracy

Free Cl

2

±0.03 mg/L ±3% of reading @ 25°C

Total Cl

2

±0.03 mg/L ±3% of reading @ 25°C

Cyanuric Acid

±1 mg/L ±15% of reading @ 25°C

pH

±0.1 pH @ 25°C

Typical EMC Deviation

±0.01 mg/L Cl

2

±1 mg/L Cyanuric Acid
±0.1 pH @ 7.0 pH

Light Source

Tungsten lamp

Light Detector

Silicon Photocell with narrow band interference filter @ 525nm.

Method

For Cl

2

: Adaptation of the USEPA method and Standard Method 4500-

Cl G. The reaction with reagents causes a pink tint in the sample.
For Cyanuric Acid: Adaptation of the turbidimetric method. The reac-

tion between cyanuric acid and the reagent causes a white suspension

in the sample.
For pH: Phenol red method. The reaction with reagents causes a red

tint in the sample.

Environment

0 to 50°C (32 to 122°F)
max 95% RH non-condensing

Battery Type

1 x 9 volt

Auto-Shut off

After 10' of non-use in

measurement mode;

after 1 hour of non-use in

calibration mode;

with last reading reminder.

Dimensions

192 x 104 x 69 mm (7.6 x 4.1 x 2.7")

Weight

360 g (12.7 oz.).

REQUIRED REAGENTS
Code Unit

Description

Quantity/test

HI 93701-0

Free Cl

2

DPD Powder Reagent

1 packet

HI 93711-0

Total Cl

2

DPD Powder Reagent

1 packet

HI 93722-0

Cyanuric Acid 1 packet

HI 93710-0

pH 5 drops

PRECISION AND ACCURACY

Precision

is how closely repeated measurements

agree with each other. Precision is usually
expressed as standard deviation (SD).
Accuracy

is defined as the nearness of a test

result to the true value.
Although good precision suggests good accuracy,
precise results can be inaccurate. The figure
explains these definitions. In a laboratory using
a standard solution of 1.00 mg/L chlorine and a
representative lot of reagent, an operator obtained
with a single instrument a standard deviation of
0.02 mg/L.