Samsung BHS6000 - Manual (Page 26)

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Transferring a call from the phone to the headset
Press the Talk button on the headset to transfer a call from the phone to the headset.
Placing a call on hold
Press and hold the Talk button to place the current call on hold.
This function is available only on the Hands-Free profile.
Answering a second call
Press the Talk button to end the first call and answer a second call. •
Press and hold the Talk button to place the first call on hold and answer a second •
call. To switch between the current call and the held call, press and hold the Talk
button.
This function is only available when using the Hands-Free profile. •
When the headset is connected with two Bluetooth phones, you cannot •
answer a second call from the same phone. It may vary depending on your
phone.