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Activating platinum electrodes – YSI TruLine ORP 50 User Manual

Page 10

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10

T 814241

04/2014

Activating platinum electrodes

TruLine

CleaningIL

Remove water-soluble contamination by rinsing with deionized water. Re-

move other contamination as follows:

Contamination

Cleaning procedure

Fat and oil

Rinse with water containing household wash-
ing-up liquid

Lime and hydroxide deposits Rinse with citric acid (10 % by weight)

After cleaning

Rinse the combination electrode with deionized water.

First-time

activation during

installation and as

required

Activating platinum electrodes

For the first-time activation use the activation powder from the SORT/RH
reagent set (component of the SORT/RH reagent set). Immerse the moist
(but not dripping) platinum electrode into the activation powder and rotate the
electrode several times in the powder. Then remove the activation powder
under flowing water with a soft brush (e.g. toothbrush).

Activation during

very long

set-up times

When changing from oxidizing to reducing test solutions and vice versa this
can result in set-up times that can take significantly more than an hour. In this
case pretreatment (activation) of the platinum surface can shorten the set-up
time. The type of pretreatment (reducing or oxidizing) is based on the pH val-
ue and the ORP voltage (U

H

) of the test solution where the latter must be es-

timated for the first measurement.

The type of pretreatment can then be determined using the following diagram
where U

H

is based on the normal hydrogen electrode:

1000

U

H

in mV

800

600

400

200

0

oxidizing pretreatment

reducing pretreatment

0

2

4

6

8

10

12

14

pH value